Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution.
نویسندگان
چکیده
A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.
منابع مشابه
Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations.
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ورودعنوان ژورنال:
- Chemical communications
دوره 11 شماره
صفحات -
تاریخ انتشار 2005